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Table 2 DTA endothermic peaks recorded in the raw material and the mixtures and their interpretations

From: Phosphogypsum waste as additives to lime stabilization of bentonite

Samples

Endothermic peaks (°C)

Mass loss (%)

Interpretations

Bentonite

135

10

Desorption of physisorbed water molecules.

520, 680

3.61, 1.17

Dehydroxylation of montmorillonite and the quartz transformation from α to β.

Lime

500

13

Decomposition of portlandite on hydrated lime (Ca(OH)2).

780

10

Calcite dycarboxylation.

PG

180

20

Gypsum dehydration (CaSO4·2H2O → γ-CaSO4).

475, 780

23

Portlandite decomposition (Ca(OH)2 → CaO + H2O).

Bentonite + 8% Lime

135

10

Desorption of physisorbed water molecules.

500, 675

10

Dehydroxylation of montmorillonite and the quartz transformation from α to β.

Bentonite + 8% Lime + 8% PG

150

10

Desorption of physisorbed water molecules.

515, 665

9

Dehydroxylation of montmorillonite and the quartz transformation from α to β.