Table 3 Kinetic constants for pyrolysis and gasification at different heating rates

 SS

147–522

k = 7.77 × 10⁴ e^47.78/RT(X)^2.62

0.91

137–529

k = 1.54 × 10⁵ e^61.01/RT(X)^3.79

0.84

 20RS:80SS

153–521

k = 5.82 × 10⁴ e^49.08/RT(X)^1.75

0.88

145–568

k = 0.82 × 10⁵ e^59.45/RT(X)^2.47

0.80

 40RS:60SS

148–513

k = 2.56 × 10⁴ e^48.62/RT(X)^0.84

0.84

151–521

k = 1.11 × 10⁷ e^78.76/RT(X)^4.21

0.86

 50RS:50SS

148–521

k = 5.75 × 10⁴ e^52.51/RT(X)^0.74

0.84

163–519

k = 1.39 × 10⁶ e^69.74/RT(X)^2.71

0.79

 RS

151–522

k = 8.56 × 10⁶  e^72.65/RT(X)^1.35

0.87

179–503

k = 5.87 × 10⁷ e^87.15/RT(X)^2.0

0.74

 SS

153–517

k = 1.37 × 10⁵ e^49.10/RT(X)^2.41

0.90

148–550

k = 1.97 × 10⁵ e^60.12/RT(X)^3.57

0.84

 20RS:80SS

173–535

k = 0.71 × 10⁵ e^48.62/RT(X)^1.52

0.86

154–659

k = 5.40 × 10⁵ e^63.73/RT(X)^3.30

0.81

 40RS:60SS

154–515

k = 0.84 × 10⁵ e^50.61/RT(X)^0.9

0.84

160–551

k = 14.4 × 10⁵ e^64.31/RT(X)^2.45

0.78

 50RS:50SS

147–516

k = 1.44 × 10⁵ e^53.07/RT(X)^0.69

0.83

160–551

k = 19.1 × 10⁵ e^68.66/RT(X)^2.26

0.80

 RS

178–500

k = 18.6 × 10⁶  e^75.40/RT(X)^1.43

0.82

166–534

k = 0.59 × 10⁸ e^89.56/RT(X)^2.12

0.71

 SS

158–560

k = 3.47 × 10⁵ e^50.47/RT(X)^2.32

0.91

153–532

k = 8.77 × 10⁵ e^64.65/RT(X)^3.39

0.84

 20RS:80SS

156–531

k = 1.67 × 10⁵ e^51.20/RT(X)^1.51

0.90

168–615

k = 5.38 × 10⁵ e^63.36/RT(X)^2.64

0.80

 40RS:60SS

157–550

k = 0.84 × 10⁵ e^50.61/RT(X)^0.90

0.84

177–550

k = 1.09 × 10⁷ e^75.28/RT(X)^3.35

0.80

 50RS:50SS

152–560

k = 1.58 × 10⁵ e^55.1032/RT(X)^1.0

0.80

175–573

k = 8.91 × 10⁶ e^73.86/RT(X)^2.82

0.80

 RS

150–548

k = 3.82 × 10⁷ e^74.01/RT(X)^0.84

0.80

190–515

k = 1.62 × 10⁸ e^88.09/RT(X)^1.90

0.70