Adsorption models | Nonlinear equation | Parameters |
---|---|---|
Isotherm | ||
Langmuir; Eq. (3) | \( {q}_e=\frac{q_m\ {K}_L\ {C}_e}{1+{K}_L\ {C}_e} \) | qe: the equilibrium loading of Ni (II) (mg g− 1), qm: the maximum loading of Ni (II) per g of adsorbent (mg g− 1), KL: constant of Langmuir equilibrium for the affinity between the adsorbent and Ni (II) (L mg− 1). |
Freundlich; Eq. (4) | \( {q}_e={K}_f\ {C}_e^n \) | Kf: constant of Freundluch for the adsorption strength ((mg g− 1) (mg L− 1)n), n: the adsorption intensity |
Temkin; Eq. (5) | qe = B ln(KT Ce) | B: the adsorption heat constant (J moL− 1); B= \( \frac{R_T\ }{b} \), R: gas constant (8.314 J mol− 1 K− 1), T: temperature (K), and KT: constant of Temkin binding (L mg− 1). |
Separation factor; Eq. (6) | \( SF=\frac{1}{1+{K}_L{C}_0} \) | SF: Separation factor (dimenstionless), C0: initial adsorbate concentration (mg L− 1). |
Kinetic | ||
pseudo-first-order; Eq. (7) | qt = qe (1 − exp(−k1 t) | k1: PFO constant rate (min− 1), t: contact time (min). |
pseudo-second-order; Eq. (8) | \( {q}_t=\frac{q_e^2\ {k}_2\ t}{1+{k}_2{q}_e\ t} \) | k2: PSO constant rate (g mg− 1 min− 1). |