Sludge source | Composition | Pyrolysis conditions/carrier gas | Pyrolysis temperature (°C) | Catalysts/microwave absorbers | Pyrolysis carbon yield (wt%) | Pyrolysis oil yield (wt%) | Pyrolysis gas yield (wt%) | Ref. |
---|---|---|---|---|---|---|---|---|
Wastewater sludge in a petrochemical plant. | Moisture: 84.9 ± 1.20 wt%; Volatile solids: 9.4 ± 0.11 wt%; Ash: 5.6 ± 0.06 wt%; Combustiblesa: 62.9 ± 1.5 wt%; Asha:37.1 ± 0.85 wt% | Multimode-microwave oven; N2; | 400–800d | Not reported | 69–51d | 16.3–20.3d | 14.8–29.5d | [6] |
Wastewater sludge in a chemical plant. | Moisture: 32.6 ± 2.5 wt%; Volatile solids: 39.3 ± 1.8 wt%; Ash: 28.1 ± 1.3 wt%; Combustiblesa: 58.3 ± 2.7 wt%; Asha:41.7 ± 3.1 wt% | 400–800d | Not reported | 65–42d | 16.2–23.8d | 8.3–37.7d | ||
Sludge in a wastewater treatment plant. | Moisture:78%; Asha: 42%;Volatile mattera: 55%; | Multimode-microwave oven; Ar; | 500–800d | Not reported | 40–36d | 45–18d | 15–46d | [12] |
Sludge in the wastewater treatment facility of a petrochemical plant. | Moisture: 84.9 ± 1.2 wt%; Solids: 15.1 ± 0.3 wt%; Volatile: solidsa: 62.9 ± 0.27 wt%; Asha: 37.5 ± 0.18 wt%; | Multimode-microwave oven; N2; | 400–800d | Not reported | 57–69d | 14–20d | 15–29d | [24] |
The dewatered high-ash sludge from. Industrial wastewater treatment plant | Moisture: 88.10 wt%; asha: 61.88 wt%; organic substancea: 38.12 wt%; for ash analysis indicated that the contents of Si, Fe, and Al were more than 10.10 wt% and all existed in the form of oxides. | Self-made single-mode and linear adjustable microwave oven; N2; | 1131.7b | SiC | 78.3 ± 3.9 | 3.0 ± 0.7 | 17.0 ± 4.8 | [29] |
919.2b | Graphitec | 84.3 ± 7.3 | 3.4 ± 0.7 | 10.8 ± 3.4 | ||||
1003.5b | Pyrolysis residues | 82.5 ± 4.5 | 3.5 ± 0.6 | 12.1 ± 5.1 | ||||
Sludge in the metropolitan wastewater treatment plant. | Moisture: 78 wt%; Asha:17.5 wt%;Volatile mattera: 82.2 wt%; Fixed carbona: 0.3 wt%; | Modified microwave oven; Vacuum; | 450–600d | ZSM-5 SiC balls | 62.3–33.0d | 16.5–28.0d | Not reported | [34] |
The remaining sludge in the 5 secondary sedimentation tank of a sewage treatment plant. | Moisture:84.3%; asha: 46.72%; organic substancea: 50.42%; fixed carbona: 2.86%; C, H, N and Sa: 28.86 wt%, 7.35 wt%, 3.88 wt% and 0.89 wt%. | Single-mode and linear adjustable microwave oven; N2; | 500–900d | Not reported | 70.0 ± 3.4–60.0 ± 2.0d | 14.5 ± 0.7–14.4 ± 0.5d | 11.3 ± 0.6–23.5 ± 1.1d | [35] |
10 wt% CaO | 65.2 ± 2.7–51.0 ± 0.8d | 15.5 ± 0.7–15.8 ± 0.6d | 17.1 ± 0.8–33.1 ± 1.6d | |||||
10 wt% Fe2O3 | 70.2 ± 2.9–55.0 ± 1.4d | 11.5 ± 0.5–14.4 ± 0.6d | 15.1 ± 0.7–29.5 ± 0.8d | |||||
Sludge in urban wastewater treatment plants. | Moisture: 80 wt%; Asha: 24.5%;Volatile mattera: 75.5%; | Multimode-microwave oven; N2; | 490c | Not reported | 39.4 | 49.8 | 10.8 | [36] |
330–1200d | 77.3–32.6d | 18.3–7.2d | 4.4–60.2d |